Evaluation Of The Performance Of Fatty Acid Methyl Ester (Fame) As An Alternative Solvent In Alkyd Resin-Based Paints

Arya Wiranata -  Politeknik Negeri Sriwijaya
Bahruddin Bahruddin* -  Universitas Riau
Zuchra Helwani -  Universitas Riau
Heni Sugesti -  Politeknik Negeri Sriwijaya
Yogi Chandra -  Politeknik Negeri Sriwijaya
Hasrul Hasrul -  Politeknik Negeri Sriwijaya
Trisuciati Syahwardini -  Politeknik Negeri Sriwijaya
Ni putu Vidya Primarista -  Politeknik Negeri Sriwijaya

Abstract


The use of conventional solvents in the oil paint industry often leads to volatile organic compound (VOC) emissions and toxicity, so this study aims to evaluate the potential of Fatty Acid Methyl Ester (FAME) as an environmentally friendly alternative solvent. FAME is synthesised from vegetable oil through a transesterification reaction, then formulated into alkyd resin-based paints with varying binder content (40%, 50%, and 60%) to be compared with acetone solvent. The paint performance evaluation includes tests on drying time, gloss level, hiding power, and Whiteness and Yellowness Index. The results show that FAME-based paints have a much higher gloss level (10–26 GU) than acetone (3–6 GU) because their slower evaporation rate provides optimal levelling time, though this results in much longer drying time, namely 780–819 minutes. In addition, FAME has been proven to produce better covering power and a lower Yellowness Index (1.39–4.15) than acetone (4.09–5.74). This superiority is influenced by the nature of FAME, which minimises damage to the polymer binder and uniformly disperses pigments, preventing agglomeration. Overall, FAME has great potential as a sustainable paint solvent that can improve optical and physical properties, although its formulation still requires optimisation to accelerate drying.

Keywords


alkyd resin, environmentally friendly solvent, fatty acid methyl ester (FAME), solvent-based paint, yellowness index.

Full Text:

PDF

References


Agbo, C., Jakpa, W., Sarkodie, B., Boakye, A., & Fu, S. (2018). A Review on the Mechanism of Pigment Dispersion. Journal of Dispersion Science and Technology, 39(6), 874–889. https://doi.org/10.1080/01932691.2017.1406367

Bielska, P., Cais-Sokolińska, D., & Dwiecki, K. (2022). Effects of Heat Treatment Duration on the Electrical Properties, Texture and Color of Polymerized Whey Protein. Molecules, 27(19), 1–10. https://doi.org/10.3390/molecules27196395

Biribicchi, C., Doutre, M., & Favero, G. (2024a). Assessing the swelling behavior of oil paint in fatty acid methyl esters (FAMEs). RSC Advances, 14(53), 39692–39699. https://doi.org/10.1039/d4ra07464e

Biribicchi, C., Doutre, M., & Favero, G. (2024b). Assessing the swelling behavior of oil paint in fatty acid methyl esters (FAMEs). RSC Advances, 14(53), 39692–39699. https://doi.org/10.1039/d4ra07464e

Biribicchi, C., Doutre, M., & Favero, G. (2024c). Characterization and assessment of cleaning systems based on fatty acid methyl esters (FAMEs) for the removal of wax-based coatings from cultural heritage objects. Materials Advances, 5(23), 9359–9375. https://doi.org/10.1039/d4ma00781f

Bonamigo Moreira, V., Rintjema, J., Bravo, F., Kleij, A. W., Franco, L., Puiggalí, J., Alemán, C., & Armelin, E. (2022). Novel Biobased Epoxy Thermosets and Coatings from Poly(limonene carbonate) Oxide and Synthetic Hardeners. ACS Sustainable Chemistry and Engineering. https://doi.org/10.1021/acssuschemeng.1c07665

Choi, J., Jang, B. N., Park, B. J., Joung, Y. K., & Han, D. K. (2014). Effect of solvent on drug release and a spray-coated matrix of a sirolimus-eluting stent coated with poly(lactic- co -glycolic acid). Langmuir. https://doi.org/10.1021/la500452h

Desrats, J. Y. (2013). Accelerating the move to waterborne coatings with sustainable additives solutions. PPCJ Polymers Paint Colour Journal.

Devale, R. R., & Mahajan, Y. S. (2024). Transesterification reactions as a means to produce esters: A critical review. Canadian Journal of Chemical Engineering, 25414. https://doi.org/10.1002/cjce.25414

Diebold, M. P. (2019). Optimizing the benefits of TiO 2 in paints. https://doi.org/10.1007/s11998-019-00295-2

Gallo-garcía, L. A., Marciano, C. H., Freire, N. V, Melo, L. F., Biaggio, F. C., Arce, P. F., Sousa, M. N., & Guimar, D. H. P. (2024). Liquid-liquid phase of imidazolium-based ionic liquids in n -butyl acetate + n -butanol mixtures : Experimental measurements , quality testing , phase stability , thermodynamic modeling. 134(December 2023), 260–270. https://doi.org/10.1016/j.jiec.2023.12.056

Ghobakhloo, S., Khoshakhlagh, A. H., Morais, S., & Mazaheri Tehrani, A. (2023). Exposure to Volatile Organic Compounds in Paint Production Plants: Levels and Potential Human Health Risks. Toxics, 11(2), 1–12. https://doi.org/10.3390/toxics11020111

Hennessy, M. G., & Münch, A. (2014). Dynamics of a slowly evaporating solvent-polymer mixture with a deformable upper surface. IMA Journal of Applied Mathematics (Institute of Mathematics and Its Applications), 79(4), 681–720. https://doi.org/10.1093/imamat/hxu024

Héritier, P. A. (2022). The Impact of Particulate Matters and Nanoparticles on Thermoplastic Polymer Coatings and Paint Layers. Polymers, 14(12). https://doi.org/10.3390/polym14122477

Hunek, R., & Franus, W. (2025). Reduction of Epoxy Resin VOCs Using Higher Fatty Acids from the Agricultural Industry: A Review. Archives of Environmental Protection, 51(1), 45–56. https://doi.org/10.24425/aep.2025.153748

Ibrahim, B., Helwani, Z., Fadhillah, I., Wiranata, A., & Miharyono, J. (2022). Properties of emulsion paint with modified natural rubber latex/polyvinyl acetate blend binder. Applied Sciences (Switzerland), 12(1). https://doi.org/10.3390/app12010296

Ibrahim, B., Helwani, Z., Wiranata, A., Fadhillah, I., Miharyono, J., & Nasruddin. (2022). Properties of Emulsion Paints with Binders Based on Natural Latex Grafting Styrene and Methyl Methacrylate. Applied Sciences (Switzerland), 12(24). https://doi.org/10.3390/app122412802

Järnström, J., Väisänen, M., Lehto, R., Jäsberg, A., Timonen, J., & Peltonen, J. (2010). Effect of latex on surface structure and wetting of pigment coatings. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 353(2–3), 104–116. https://doi.org/10.1016/j.colsurfa.2009.11.001

Kaczmarek-Szczepańska, B., Zasada, L., & Grabska-Zielińska, S. (2022). The Physicochemical, Antioxidant, and Color Properties of Thin Films Based on Chitosan Modified by Different Phenolic Acids. Coatings, 12(2), 1–9. https://doi.org/10.3390/coatings12020126

Karakaş, F., Vaziri Hassas, B., & Çelik, M. S. (2015). Effect of precipitated calcium carbonate additions on waterborne paints at different pigment volume concentrations. Progress in Organic Coatings, 83, 64–70. https://doi.org/10.1016/j.porgcoat.2015.02.003

Kim, M. H., Lee, J. B., & Choi, K. Y. (2013). Discoloration mechanism of UV-curable polymer/metal hybrid coating. Journal of Industrial and Engineering Chemistry. https://doi.org/10.1016/j.jiec.2012.08.014

Koleske, J. V. (1995). Paint and Coating Testing Manual, Fourteenth Edition of the Gardner-Sward Handbook. In Paint and Coating Testing Manual, Fourteenth Edition of the Gardner-Sward Handbook. https://doi.org/10.1520/mnl17_14th-eb

Mossige, E. J., Suja, V. C., Islamov, M., Wheeler, S. F., Fuller, G. G., Taylor, E. R., & Fuller, G. G. (2020). Evaporation-induced Rayleigh-Taylor instabilities in polymer solutions: Rayleigh-Taylor Instabilities.

Nameer, S., Deltin, T., Sundell, P.-E., & Johansson, M. (2019). Bio-based multifunctional fatty acid methyl esters as reactive diluents in coil coatings. Progress in Organic Coatings, 136. https://doi.org/10.1016/j.porgcoat.2019.105277

Pereira, C. S. M., Silva, V. M. T. M., & Rodrigues, A. E. (2011). Ethyl lactate as a solvent: Properties, applications and production processes – a review. Green Chemistry, 13(10), 2658–2671. https://doi.org/10.1039/c1gc15523g

Poós, T., & Varju, E. (2024). New dimensionless equation for mass transfer at acetone evaporation under forced convection. International Communications in Heat and Mass Transfer, 159(August). https://doi.org/10.1016/j.icheatmasstransfer.2024.107961

Reetz, M. T., & König, G. (2021). n-Butanol: An Ecologically and Economically Viable Extraction Solvent for Isolating Polar Products from Aqueous Solutions. In European Journal of Organic Chemistry. https://doi.org/10.1002/ejoc.202100829

Salehpour, S., & Dubé, M. A. (2008). The use of biodiesel as a green polymerization solvent at elevated temperatures. Polymer International. https://doi.org/10.1002/pi.2413

Soucek, M. D., Khattab, T., & Wu, J. (2012). Review of autoxidation and driers. Progress in Organic Coatings, 73(4), 435–454. https://doi.org/10.1016/j.porgcoat.2011.08.021

Stoye, D., & Freitag, W. (2008). Paints , Coatings and Solvents.

Sun, Q., Bao, X., Liang, Q., Xu, W., Zhang, Q., Zou, X., Huang, C., Shen, C., & Chu, Y. (2022). Qualitative and quantitative determination of butanol in latex paint by fast gas chromatography proton transfer reaction mass spectrometry. Journal of Chromatography A, 1676. https://doi.org/10.1016/j.chroma.2022.463210

Van Gorkum, R., & Bouwman, E. (2005). The oxidative drying of alkyd paint catalysed by metal complexes. Coordination Chemistry Reviews, 249(17-18 SPEC. ISS.), 1709–1728. https://doi.org/10.1016/j.ccr.2005.02.002

Wicks, Z. W., Jones, F. N., Pappas, S. P., & Wicks, D. A. (2006). Organic Coatings: Science and Technology. In Organic Coatings: Science and Technology. https://doi.org/10.1002/9780470079072

Zaratti, C., Marinelli, L., Colasanti, I. A., Barbaccia, F. I., Aureli, H., Prestileo, F., de Caro, T., La Russa, M. F., & Macchia, A. (2024a). Evaluation of Fatty Acid Methyl Esters (FAME) as a Green Alternative to Common Solvents in Conservation Treatments. Applied Sciences (Switzerland), 14(5). https://doi.org/10.3390/app14051970

Zaratti, C., Marinelli, L., Colasanti, I. A., Barbaccia, F. I., Aureli, H., Prestileo, F., de Caro, T., La Russa, M. F., & Macchia, A. (2024b). Evaluation of Fatty Acid Methyl Esters (FAME) as a Green Alternative to Common Solvents in Conservation Treatments. Applied Sciences (Switzerland), 14(5). https://doi.org/10.3390/app14051970




DOI: https://doi.org/10.24952/lavoisier.v5i1.20037

Refbacks

  • There are currently no refbacks.


Copyright (c) 2026 Arya - Wiranata

Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.


Journal Lavoisier: Chemistry Education Journal, The Infomation and Files Indexed by:
Flag Counter
Creative Commons License

Lavoisier:Chemistry Education Journal is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License. Copyright © 2022 Lavoisier: Chemistry Education Journal.All rights reserved.


Journal Lavoisier: Chemistry Education Journal, The Infomation and Files Supported by: